catena-Poly[μ2-iodido-diiodidobis(μ3-pyridine-2-thione-κ3 S:S:S)(μ2-pyridine-2-thione-κ2 S:S)tricopper(I)] – ScienceOpen
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      catena-Poly[μ 2-iodido-diiodidobis(μ 3-pyridine-2-thione-κ 3 S: S: S)(μ 2-pyridine-2-thione-κ 2 S: S)tricopper(I)]

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          Abstract

          In the title compound, [Cu 3I 3(C 5H 5NS) 3] n , a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu 3S 3] and [Cu 2S 2] rings sharing Cu—S edges, with the [Cu 2S 2] rings located about inversion centers. Cu I atoms bridged by iodide ions exhibit the shortest Cu⋯Cu separation in the polymer [2.8590 (14) Å]. The three independent Cu I atoms all display distorted tetra­hedral coordination geometries.

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          Author and article information

          Journal
          Acta Crystallogr Sect E Struct Rep Online
          Acta Crystallogr Sect E Struct Rep Online
          Acta Cryst. E
          Acta Crystallographica Section E: Structure Reports Online
          International Union of Crystallography
          1600-5368
          01 February 2013
          09 January 2013
          09 January 2013
          : 69
          : Pt 2 ( publisher-idID: e130200 )
          : m87
          Affiliations
          [a ]College of Pharmacy, Fujian Medical University, Fuzhou 350004, People’s Republic of China
          [b ]Xiamen Maternity and Child Health Care Hospital, Xiamen 361001, People’s Republic of China
          Author notes
          Correspondence e-mail: carsten.ke@ 123456hotmail.com
          Article
          bh2469 ACSEBH S1600536812052051
          10.1107/S1600536812052051
          3569186
          23424430
          18f46fc8-776e-4406-8eae-603a8d680792
          © Ke and Wu 2013

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 29 November 2012
          : 29 December 2012
          Categories
          Metal-Organic Papers

          Materials characterization
          Materials characterization

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