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      Synthesis of New 1,2,3-Triazole Derivatives of Uracil and Thymine with Potential Inhibitory Activity against Acidic Corrosion of Steels

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          Abstract

          Ten 1,4-disubstituted 1,2,3-triazoles were synthesized from one of 1-(azido-methyl)benzene, 1-(azidomethyl)-4-fluorobenzene, 1-(azidomethyl)-4-chlorobenzene, 1-(azidomethyl)-4-bromobenzene or 1-(azidomethyl)-4-iodobenzene, generated in situ from sodium azide and the corresponding benzyl halide, and dipropargyl uracil or dipropargyl thymine. Optimal experimental conditions were established for the conventional click chemistry. The corrosion inhibiting properties of some of these compounds, which were determined by means of an electrochemical technique, are also presented.

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          Cu(I)-catalyzed Huisgen azide-alkyne 1,3-dipolar cycloaddition reaction in nucleoside, nucleotide, and oligonucleotide chemistry.

          F Amblard, Raymond F. Schinazi, Raymond J Cho (2009)
          Article 0 comments Cited 128 times – based on 0 reviews     Review now
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            Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium

            Bao-rong Hou, Wei-hua Li, Chang-ling Pei … (2008)
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              Corrosion control of mild steel using 3,5-bis(4-methoxyphenyl)-4-amino-1,2,4-triazole in normal hydrochloric acid medium

              Fouad Bentiss, Charafeddine Jama, Bouchaib Mernari … (2009)
              Article 0 comments Cited 93 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Journal ID (nlm-ta): Molecules
                Journal ID (iso-abbrev): Molecules
                Journal ID (publisher-id): molecules
                Title: Molecules
                Publisher: MDPI
                ISSN (Electronic): 1420-3049
                Publication date (Electronic): 18 April 2013
                Publication date Collection: April 2013
                Volume: 18
                Issue: 4
                Pages: 4613-4627
                Affiliations
                [1 ]Departamento de Ciencias Básicas, Universidad Autónoma Metropolitana, Av. San Pablo No. 180, México D.F., C.P. 02200, Mexico; E-Mails: rogo@ 123456correo.azc.uam.mx (R.G.-O.); dab@ 123456correo.azc.uam.mx (D.A.-B.); ponque.chem@ 123456gmail.com (N.M.-C.); arasv_21@ 123456hotmail.com (A.E.-V.)
                [2 ]Departamento de Materiales, Universidad Autónoma Metropolitana, Av. San Pablo No. 180, México D.F., C.P. 02200, Mexico; E-Mails: mepp@ 123456correo.azc.uam.mx (M.E.P.-P.); mmrr@ 123456correo.azc.uam.mx (M.A.R.-R.)
                [3 ]Departamento de Química, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Apartado Postal 14-740, 07000 México D.F., Mexico; E-Mail: rsantill@ 123456cinvestav.mx
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: gns@ 123456correo.azc.uam.mx ; Tel.: +52-55-5318-9593; Fax: +52-55-5318-9000.
                Article
                Publisher ID: molecules-18-04613
                DOI: 10.3390/molecules18044613
                PMC ID: 6269733
                PubMed ID: 23599018
                SO-VID: 2d8a7c31-f3bb-4672-b800-0fe3f1b07f88
                Copyright © © 2013 by the authors; licensee MDPI, Basel, Switzerland.
                License:

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                Date received : 26 January 2013
                Date revision received : 11 April 2013
                Date accepted : 16 April 2013
                Categories
                Subject: Article

                Keywords: synthesis,triazoles,pyrimidines,biological,corrosion
                Data availability:
                Keywords: synthesis, triazoles, pyrimidines, biological, corrosion

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