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      Synthesis of New 1,2,3-Triazole Derivatives of Uracil and Thymine with Potential Inhibitory Activity against Acidic Corrosion of Steels

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          Abstract

          Ten 1,4-disubstituted 1,2,3-triazoles were synthesized from one of 1-(azido-methyl)benzene, 1-(azidomethyl)-4-fluorobenzene, 1-(azidomethyl)-4-chlorobenzene, 1-(azidomethyl)-4-bromobenzene or 1-(azidomethyl)-4-iodobenzene, generated in situ from sodium azide and the corresponding benzyl halide, and dipropargyl uracil or dipropargyl thymine. Optimal experimental conditions were established for the conventional click chemistry. The corrosion inhibiting properties of some of these compounds, which were determined by means of an electrochemical technique, are also presented.

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          Cu(I)-catalyzed Huisgen azide-alkyne 1,3-dipolar cycloaddition reaction in nucleoside, nucleotide, and oligonucleotide chemistry.

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            Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium

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              Corrosion control of mild steel using 3,5-bis(4-methoxyphenyl)-4-amino-1,2,4-triazole in normal hydrochloric acid medium

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                Author and article information

                Journal
                Molecules
                Molecules
                molecules
                Molecules
                MDPI
                1420-3049
                18 April 2013
                April 2013
                : 18
                : 4
                : 4613-4627
                Affiliations
                [1 ]Departamento de Ciencias Básicas, Universidad Autónoma Metropolitana, Av. San Pablo No. 180, México D.F., C.P. 02200, Mexico; E-Mails: rogo@ 123456correo.azc.uam.mx (R.G.-O.); dab@ 123456correo.azc.uam.mx (D.A.-B.); ponque.chem@ 123456gmail.com (N.M.-C.); arasv_21@ 123456hotmail.com (A.E.-V.)
                [2 ]Departamento de Materiales, Universidad Autónoma Metropolitana, Av. San Pablo No. 180, México D.F., C.P. 02200, Mexico; E-Mails: mepp@ 123456correo.azc.uam.mx (M.E.P.-P.); mmrr@ 123456correo.azc.uam.mx (M.A.R.-R.)
                [3 ]Departamento de Química, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Apartado Postal 14-740, 07000 México D.F., Mexico; E-Mail: rsantill@ 123456cinvestav.mx
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: gns@ 123456correo.azc.uam.mx ; Tel.: +52-55-5318-9593; Fax: +52-55-5318-9000.
                Article
                molecules-18-04613
                10.3390/molecules18044613
                6269733
                23599018
                2d8a7c31-f3bb-4672-b800-0fe3f1b07f88
                © 2013 by the authors; licensee MDPI, Basel, Switzerland.

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                : 26 January 2013
                : 11 April 2013
                : 16 April 2013
                Categories
                Article

                synthesis,triazoles,pyrimidines,biological,corrosion
                synthesis, triazoles, pyrimidines, biological, corrosion

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