An octahedral tetrachlorido Fe(ii) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures.

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Abstract

An air stable, neutral Fe(ii) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three-dimensional non-covalent network composed of halogen bonding and π-π stacking promotes magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.

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Journal

Journal ID (iso-abbrev): Dalton Trans

Title: Dalton transactions (Cambridge, England : 2003)

Publisher: Royal Society of Chemistry (RSC)

ISSN (Electronic): 1477-9234

ISSN (Print): 1477-9226

Publication date (Electronic): Jun 12 2018

Volume: 47

Issue: 23

Affiliations

[1 ] School of Science and Technology, Nottingham Trent University, NG11 8NS, Nottingham, UK. anthony.fitzpatrick@ntu.ac.uk.

Article

DOI: 10.1039/c8dt01401a

PubMed ID: 29796507

SO-VID: 71c60031-2185-434b-a2b4-d87eec010016

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